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- W1488923400 abstract "Abstract The dissolution mechanism of thoria in nitric-hydrofluoric acid has been investigated and the relationships between dissolution rate and fluoride concentration both in solution and on the thoria surface have been determined. An interpretation of these results based on the dissociation of surface hydroxyl groups is used to support two proposed steps of the reaction mechanism. The first is the adsorption of fluoride onto the thoria surface and the second is the reaction of fluoride from solution with these sites prior to desorption. This work shows that studies of dissolution mechanisms of oxides should always be accompanied by measurements of the adsorption of the anions taking part." @default.
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- W1488923400 date "1970-11-01" @default.
- W1488923400 modified "2023-09-23" @default.
- W1488923400 title "Oxide dissolution mechanisms—I" @default.
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- W1488923400 doi "https://doi.org/10.1016/0022-1902(70)80158-0" @default.
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