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- W1489105055 abstract "The homopolymerization of 5-alkyl-2-norbornenes and their copolymerization with norbornene have been successfully carried out employing Pd(acac)2/PPh3/BF3OEt2 catalyst system. The activity of the catalyst system is comparable to that of most active late-transition metal catalysts described in the literature. The molecular weight distributions of homo- and copolymers indicate a single-site, highly homogeneous character of the active catalyst species. The incorporation of flexible alkyl groups onto the main chain of norbornene as well as copolymerization of 5-alkyl-2-norbornenes with norbornene represent useful methods for lowering the glass transition temperature (Tg), i.e. improving the processability. The simplicity of catalytic system composition might be of industrial importance." @default.
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- W1489105055 date "2005-05-01" @default.
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- W1489105055 title "Homopolymerization of 5-alkyl-2-norbornenes and their copolymerization with norbornene over novel Pd(acac)2/PPh3/BF3OEt2 catalyst system" @default.
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- W1489105055 doi "https://doi.org/10.1016/j.polymer.2005.02.112" @default.
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