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• W1489424710 startingPage "14464" @default.
• W1489424710 abstract "The objectives of this study were to evaluate the binding behavior of Cu(II) and Eu(III) with water extractable organic matter (WEOM) in soil, and assess the competitive effect of the cations. Excitation-emission matrix (EEM) fluorescence spectrometry was used in combination with parallel factor analysis (PARAFAC) to obtain four WEOM components: fulvic-like, humic-like, microbial degraded humic-like, and protein-like substances. Fluorescence titration experiments were performed to obtain the binding parameters of PARAFAC-derived components with Cu(II) and Eu(III). The conditional complexation stability constants (logKM) of Cu(II) with the four components ranged from 5.49 to 5.94, and the Eu(III) logKM values were between 5.26 to 5.81. The component-specific binding parameters obtained from competitive binding experiments revealed that Cu(II) and Eu(III) competed for the same binding sites on the WEOM components. These results would help understand the molecular binding mechanisms of Cu(II) and Eu(III) with WEOM in soil environment." @default.
• W1489424710 created "2016-06-24" @default.
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• W1489424710 date "2015-06-25" @default.
• W1489424710 modified "2023-09-26" @default.
• W1489424710 title "Evaluation of the Interactions between Water Extractable Soil Organic Matter and Metal Cations (Cu(II), Eu(III)) Using Excitation-Emission Matrix Combined with Parallel Factor Analysis" @default.
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• W1489424710 doi "https://doi.org/10.3390/ijms160714464" @default.
• W1489424710 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4519852" @default.
• W1489424710 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26121300" @default.
• W1489424710 hasPublicationYear "2015" @default.
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