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- W1489705869 abstract "Qualitative MO concepts and explicit model MO calculations predict unusual electronic structures, very high energies and anomalous reactivity patterns for dicoordinate, mononuclear bisphosphane complexes of Pt(0) if the metal center of such 14 electron fragments (d10-ML2, normally linear) can be incorporated into a four-membered PtPCP chelate ring, thus enforcing a P-Pt-P angle at or below 75°. The choice of appropriate, specific di-phosphinomethane ligands (dtbpm, dcpm) allows the experimental generation of [(dtbpm)Pt(O)] and [(dcpm)Pt(O)] as tailor-made reactive intermediates, which, despite their extreme ring strain, have a sufficient lifetime to be trapped in fascinating, often unprecedented bond activation reactions with - among other substrates - various organosilanes. Preparative and mechanistic aspects of their bond insertion chemistry are reported." @default.
- W1489705869 created "2016-06-24" @default.
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- W1489705869 date "2005-07-26" @default.
- W1489705869 modified "2023-10-03" @default.
- W1489705869 title "Organosilane Chemistry at Tailor‐Made Platinum Centers" @default.
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- W1489705869 doi "https://doi.org/10.1002/9783527620777.ch50" @default.
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