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- W1489764138 abstract "This thesis concerns the involvement of transition metal chemistry in nanoscale devices.Chapter 1 describes the surprising synthesis of iron oxide nanoparticles from iron(III) salts and the oligopyridine, 2,2'-bipyridine. The synthesis of the nanoparticles is optimised and they are characterised using a variety of techniques.Chapter 2 regards the synthesis and photophysical behaviour of a family of n-pyridyl-terpyridine ligands and some of their metal complexes. One of the complexes is shown to be a suitable light harvesting dye for use in a photocatalytic water splitting system.Chapter 3 features details on a synthetic strategy to construct a full-adder molecular device. Chapter 4 concerns investigations into the limitations of a previously reported facile synthesis of 4'-substituted terpyridines. A combination of aromatic and aliphatic substrates are tested. In-situ infrared spectroscopy is also used to probe the kinetics of these types of reactions." @default.
- W1489764138 created "2016-06-24" @default.
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- W1489764138 date "2010-01-01" @default.
- W1489764138 modified "2023-09-26" @default.
- W1489764138 title "Investigations of nanoscale devices involving transition metal chemistry" @default.
- W1489764138 doi "https://doi.org/10.5451/unibas-005293041" @default.
- W1489764138 hasPublicationYear "2010" @default.
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