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- W1489887921 abstract "By using high performance size exclusion chromatography (HPSEC), conformational changes of humic substances were observed with increases of humic solution concentration. Weak dispersive forces are the cause of attraction among humic molecules when in dilute solutions. Conversely, electrostatic repulsion between negatively charged humic molecules occurs as the concentration increases. This behavior is consistent with the model that describes humic substances as supramolecular associations of self-assembling small molecules rather than as macromolecular polymers or regular micelles. In fact, the concentrations used to perform the experiments were larger than 0.05 g.L−1, that is the concentration above which conformational changes should not be observed, according to the model of humic macropolymeric coils. Moreover, all concentrations used were well below the humic critical micellar concentration of 10 g.L−1 that is reported to be the critical micelle concentration (CMC) at which humic substances may start to form micelles in solution." @default.
- W1489887921 created "2016-06-24" @default.
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- W1489887921 date "2002-01-01" @default.
- W1489887921 modified "2023-09-23" @default.
- W1489887921 title "Effect of concentration on the self-assembling of dissolved humic substances" @default.
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- W1489887921 doi "https://doi.org/10.1016/s0166-2481(02)80064-2" @default.
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