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- W1490040186 abstract "This chapter reviews the developments in imidazole chemistry and discusses condensed imidazoles (such as benzimidazole, purines, etc.), and compounds containing reduced imidazole rings. The methods for the syntheses of the imidazole ring system are also presented. Physical properties of imidazole and its derivatives such as dipole moments; melting points, boiling points, and solubilities; acid and basic strength; crystal structure; UV spectra; IR and Raman spectra; NMR spectra; mass spectrometry; electron spin resonance; optical rotatory dispersion and polarography; chromatography; thermodynamic data; and quantum mechanical calculations are described. In addition, the chemical properties such as structure; aromatic character and reactivity; electrophilic substitution reactions; nucleophilic attack; reactions involving radicals; reactions of substituents on ring carbon atoms; reactions of substituents on ring nitrogen atoms; and miscellaneous properties of imidazole and its derivatives are illustrated. Most of the reactions and properties of 1-substituted imidazoles have been discussed. Apart from the utilization of the readily removable benzyl substituent in synthetic procedures leading to 2-substituted imidazoles, perhaps the most exciting advances have stemmed from the reactions of the 1 -acylimidazoles (imidazolides), which are extremely reactive in such nucleophilic reactions as hydrolysis and alcoholysis." @default.
- W1490040186 created "2016-06-24" @default.
- W1490040186 creator A5021026162 @default.
- W1490040186 date "1970-01-01" @default.
- W1490040186 modified "2023-10-11" @default.
- W1490040186 title "Advances in Imidazole Chemistry" @default.
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