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- W1490207838 abstract "Novel, mixed substituted organogallium compounds of the type (R1)(R2)Ga[(CH2)3NR2] (R1, R2 Cl, BH4, alkyl, (η5-C5H5)(CO)2Fe; R CH3, C2H5) have been synthesized and fully characterized. These compounds are stabilized by intramolecular adduct formation at the gallium centre. The solid state structures of [(η5-C5H5)(CO)2]FeGa[(CH2)3N(CH3)2](R1) (3a: R1 C2H5; 3d: R1 BH4) exhibit FeGa bond lengths of 245.65(4) pm and 237.5(1) pm respectively. The GaB distance in 3d amounts to 237.4(3) pm. Remarkably pure Fe/Ga thin films were grown from 3d by low pressure OMCVD. The BH4 group reduces both the decomposition temperature of the single source precursor and the degree of contamination by carbon of the mixed metal thin films." @default.
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- W1490207838 date "1993-10-01" @default.
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- W1490207838 title "Organo Group 13 metal complexes of d-block elements" @default.
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- W1490207838 doi "https://doi.org/10.1016/0022-328x(93)86056-n" @default.
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