FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W149025862> ?p ?o ?g. }

• W149025862 abstract "In this study, we have synthesized two families of new carbohydrate-based amphiphilic derivatives: a series of alkyl glucoside ethers varying in terms of chain length and position on the sugar, and a series of glucosteroids varying in terms of alkyl spacer and, for the disutibstuted systems, in terms of alkyl side chain length. By the means of analytical methods, such as NMR spectroscopy, mass spectroscopy and elementary analysis, the structure of all the compounds was carefully established, as well as their purity. Their liquid crystalline behaviors were studied by the means of transmission light microscopy and differential scanning calorimetry. The two families of compounds which have been studied illustrate how much the behavior can be essentially related to polar interactions (H-bonding), therefore to the sugar moiety, for the ether series, or to hydrophobic interactions (lipid-lipid) in the glucosteroid series. In this latter series, preference for either steroid-stroid or steroid alkyl packing appears as an insight in understanding the behavior of complex lipids, showing potentially more than one conformational structure with important consequences on the supramolecular level, therefore to their potential biological role. This could be regarded as “lipid denaturation” by analogy to the protein denaturation. Also, when we see that compounds like the glycosteroids having an long chain ester -CAG, BbGL-I, are found to exist in Nature, and how much glycolipid-cholesterol interactions were recently shown to be critical in some biological processes, it is hoped that our observations can provide a new vision angle for the study of complex lipids and glycolipids. As a start to develop new probes targeting the “lipid raft” microdomain in membranes, we also explored a sequence towards carbohydrate laurdan hybrids. Further development of this strategy and evaluation of the biological properties is programmed within new collaborative projects." @default.
• W149025862 created "2016-06-24" @default.
• W149025862 creator A5003711562 @default.
• W149025862 date "2013-02-28" @default.
• W149025862 modified "2023-09-22" @default.
• W149025862 title "On the role of the carbohydrate vs the lipid moieties in neoglycolipid self-organisation : Synthesis and liquid crystalline properties of two new families of carbohydrate-based amphiphiles" @default.
• W149025862 cites W138892581 @default.
• W149025862 cites W1492939789 @default.
• W149025862 cites W1822877171 @default.
• W149025862 cites W1964072789 @default.
• W149025862 cites W1964843466 @default.
• W149025862 cites W1967257557 @default.
• W149025862 cites W1975613940 @default.
• W149025862 cites W1981983624 @default.
• W149025862 cites W1982413953 @default.
• W149025862 cites W1983120955 @default.
• W149025862 cites W1985456303 @default.
• W149025862 cites W1988181603 @default.
• W149025862 cites W1988802512 @default.
• W149025862 cites W2004994771 @default.
• W149025862 cites W2005892204 @default.
• W149025862 cites W2005967681 @default.
• W149025862 cites W2007584407 @default.
• W149025862 cites W2011566865 @default.
• W149025862 cites W2017020122 @default.
• W149025862 cites W2017114028 @default.
• W149025862 cites W2019682843 @default.
• W149025862 cites W2020497598 @default.
• W149025862 cites W2021356998 @default.
• W149025862 cites W2022753814 @default.
• W149025862 cites W2026662411 @default.
• W149025862 cites W2027107547 @default.
• W149025862 cites W2028336439 @default.
• W149025862 cites W2030211379 @default.
• W149025862 cites W2035832464 @default.
• W149025862 cites W2040536531 @default.
• W149025862 cites W2041083224 @default.
• W149025862 cites W2045554034 @default.
• W149025862 cites W2051230202 @default.
• W149025862 cites W2051511277 @default.
• W149025862 cites W2052220163 @default.
• W149025862 cites W2057001286 @default.
• W149025862 cites W2061450617 @default.
• W149025862 cites W2061533689 @default.
• W149025862 cites W2065886456 @default.
• W149025862 cites W2067691579 @default.
• W149025862 cites W2067845342 @default.
• W149025862 cites W2073859425 @default.
• W149025862 cites W2081914357 @default.
• W149025862 cites W2091053153 @default.
• W149025862 cites W2092237875 @default.
• W149025862 cites W2092592913 @default.
• W149025862 cites W2093534313 @default.
• W149025862 cites W2095104116 @default.
• W149025862 cites W2099735432 @default.
• W149025862 cites W2100520064 @default.
• W149025862 cites W2106207152 @default.
• W149025862 cites W2110932882 @default.
• W149025862 cites W2112795553 @default.
• W149025862 cites W2120611967 @default.
• W149025862 cites W2123363039 @default.
• W149025862 cites W2126941937 @default.
• W149025862 cites W2135311979 @default.
• W149025862 cites W2136558879 @default.
• W149025862 cites W2144519884 @default.
• W149025862 cites W2145842550 @default.
• W149025862 cites W2156921637 @default.
• W149025862 cites W2157487352 @default.
• W149025862 cites W2159047621 @default.
• W149025862 cites W2161068862 @default.
• W149025862 cites W2171991204 @default.
• W149025862 cites W2314327436 @default.
• W149025862 cites W2318513433 @default.
• W149025862 cites W2330311845 @default.
• W149025862 cites W2951296715 @default.
• W149025862 hasPublicationYear "2013" @default.
• W149025862 type Work @default.
• W149025862 sameAs 149025862 @default.
• W149025862 citedByCount "0" @default.
• W149025862 crossrefType "dissertation" @default.
• W149025862 hasAuthorship W149025862A5003711562 @default.
• W149025862 hasConcept C121332964 @default.
• W149025862 hasConcept C15920480 @default.
• W149025862 hasConcept C178790620 @default.
• W149025862 hasConcept C185592680 @default.
• W149025862 hasConcept C2776568683 @default.
• W149025862 hasConcept C2778977261 @default.
• W149025862 hasConcept C2780263894 @default.
• W149025862 hasConcept C32909587 @default.
• W149025862 hasConcept C39519442 @default.
• W149025862 hasConcept C521977710 @default.
• W149025862 hasConcept C66974803 @default.
• W149025862 hasConcept C67407626 @default.
• W149025862 hasConcept C71240020 @default.
• W149025862 hasConcept C8010536 @default.
• W149025862 hasConcept C93275456 @default.
• W149025862 hasConcept C97355855 @default.
• W149025862 hasConceptScore W149025862C121332964 @default.
• W149025862 hasConceptScore W149025862C15920480 @default.
• W149025862 hasConceptScore W149025862C178790620 @default.

• next