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- W1490276988 abstract "The existence of dissociation plateaus in the pressure-composition isotherms for hydrogen absorption in amorphous metals is shown to depend on the degree of configurational disorder in the host lattice. Within a mean-field approximation for the attractive elastic hydrogen-hydrogen interaction, the Stoner-type condition $ensuremath{-}an({E}_{0})ensuremath{ge}1$ is derived for the existence of a positive critical temperature ${T}_{c}$ [$a$ is a measure of the strength of the effective hydrogen-hydrogen interaction and $n({E}_{0})$ is the maximum of the symmetric density-of-sites function $n(E)$ which describes the spread in the energy of the sites which can be occupied by hydrogen atoms]. Analytical expressions for ${T}_{c}$ are derived for a square and a doublesquare density-of-sites function. These simple models for $n(E)$ are used to reproduce experimental results on crystalline and amorphous nickel-zirconium hydrides." @default.
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- W1490276988 date "1983-06-15" @default.
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- W1490276988 title "Phase separation in amorphous metal hydrides: A Stoner-type criterion" @default.
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- W1490276988 doi "https://doi.org/10.1103/physrevb.27.7575" @default.
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