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- W1491109675 abstract "Molecular absorption with electrothermal volatilization in a graphite tube. Part 3. A study of the determination of fluoride traces by A1F, GaF, InF and T1F molecular absorption. The use of the molecular absorption of thermally stable molecules such as AlF, GaF, InF and TlF, generated in a normal graphite tube, is assessed for determinations of fluoride. Optimal experimental conditions are discussed. The presence of Na+ ions increases the signals. The influence of Na+ ions and of other substances is discussed. The sensitivities (0.01 absorbance) are 0.4 ng F- for AlF, 0.8 ng F- for GaF, and 1.1 ng F- for InF. Es wurde die Anwendbarkeit der Molekülabsorption thermisch stabiler Moleküle, wie AlF, GaF, InF und TlF, die in einer normalen Graphitrohrküvette erzeugt wurden, für die Bestimmung des Fluorids untersucht. Die experimentellen Bedingungen wurden optimiert. Es ist möglich, Fluoridspuren in Mikrovolumina zu bestimmen. Die Gegenwart von Na+-ionen erhöht die Signale. Der Einfluß der Na+-ionen und auch von anderen Substanzen auf die Molekülabsorption wird diskutiert. Die reziproken Empfindlichkeiten bezogen auf 0,01 Extinktion sind: AlF 0,4 ng F-; GaF 0,8 ng F-; InF 1,1 ng F-." @default.
- W1491109675 created "2016-06-24" @default.
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- W1491109675 date "1979-12-01" @default.
- W1491109675 modified "2023-10-14" @default.
- W1491109675 title "Molekülabsorptionsspektrometrie bei elektro-thermischer verdampfung in einer graphitrohrküvette" @default.
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- W1491109675 doi "https://doi.org/10.1016/s0003-2670(01)93254-4" @default.
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