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- W149117740 abstract "Publisher Summary This chapter discusses the occurrence and biosynthesis of branched-chain sugars. Apiose is a branched chain sugar that occurs widely in the plant kingdom. The precursor is UDP-D-glucuronic acid; loss of the carboxyl group and expulsion of C-3 gives UDP-D-apiose. The enzymatic product is carefully characterized. It easily decomposes under alkaline conditions to the 1:2 cyclic phosphate α -D- apio -D-furanosyl 1:2 cyclic phosphate.The results of the binding studies are interpreted as follows. In the course of the normal reaction UDP - glucuronic acid is bound first. This process causes a conformational change of the enzyme that then enables NAD + to bind second. A similar conformational change is caused by the binding of UDP. The pronounced differences in pH optima of the synthase and lyase, and the difference in light stimulation led to the assumption that enzymes can be localized in different cell compartments. However, differential centrifugation of lysed protoplasts from parsley cell cultures or from young parsley leaves gave no indication for the localization of one of the enzyme in a particulate fraction." @default.
- W149117740 created "2016-06-24" @default.
- W149117740 creator A5056471622 @default.
- W149117740 date "1980-01-01" @default.
- W149117740 modified "2023-10-18" @default.
- W149117740 title "Branched-Chain Sugars: Occurrence and Biosynthesis" @default.
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- W149117740 doi "https://doi.org/10.1016/b978-0-12-675403-2.50011-9" @default.
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