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- W1492509715 abstract "The optical rotations of two families of compounds, both having the 1,6-anhydro-β-d-hexopyranose structure as the fundamental skeletal unit, have been expressed as algebraic summations of empirical rotatory contributions from various conformational elements of asymmetry. The calculations have been made for 1,6-anhydro-monodeoxy-β-d-hexopyranoses and their diacetates, and for the 2,7-anhydro-β-d-heptulopyranoses and their tetraacetates, by using terms calculated1 for the parent 1,6-anhydro-β-d-hexopyranoses and four new terms to describe interactions previously untreated. The calculated rotations are in satisfactory agreement with constants reported in the literature, and indicate conformational uniformity throughout the entire class of examples." @default.
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- W1492509715 date "1970-07-01" @default.
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- W1492509715 title "Calculation of molecular rotation by summation of partial conformational contributions" @default.
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- W1492509715 doi "https://doi.org/10.1016/s0008-6215(00)80702-8" @default.
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