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- W1492554598 abstract "We consider a PEM fuel cell with concentric circular electrodes: the small anode and the large cathode. A model for in-plane distributions of the cathode overpotential ηc and the membrane potential Φ in the anode-free region of the cell is developed. Mathematically, the problem reduces to the axially symmetric Poisson–Boltzmann equation for ηc. An approximate analytical solution shows that |ηc| exhibits rapid decay to zero with the radius, while |Φ| grows to the value of |η0c|, the cathode overpotential in the working domain of the cell. For typical η0c, the radial shape of ηc far from the anode edge only weakly depends on η0c; this effect is analogous to Debye screening in plasmas. The smaller the anode radius, the faster Φ approaches η0c with the distance from the anode. It follows, that a reference electrode for measuring the cathode overpotential in the working area can be placed at a small distance from the curved anode edge." @default.
- W1492554598 created "2016-06-24" @default.
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- W1492554598 date "2015-01-01" @default.
- W1492554598 modified "2023-09-23" @default.
- W1492554598 title "Potentials Near a Curved Anode Edge in a PEM Fuel Cell: Analytical Solution for Placing a Reference Electrode" @default.
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- W1492554598 doi "https://doi.org/10.1149/2.0331510jes" @default.
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