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- W1493783459 abstract "The neutron first-order difference method has been used to determine the Cu2+-D2O and Cl--D2O coordination in 4.32 molal (mol kg-1) CuCl2 and the Cu2+-D2O coordination in 2.00 molal Cu(ClO4)2. In the copper chloride solution the Cu2+ near-neighbour distances are given by rCuO=1.96+or-0.03 AA and rCuD=2.54+or-0.03 AA and the hydration number is nO=3.4+or-0.2. The Cl- coordination is described by distances rClD(1)=2.27+or-0.03 AA and rCuO=3.25+or-0.05 AA and a hydration number nD=3.3+or-0.4. In the case of the perchlorate solution a Cu2+ near-neighbour distance of rCuO=1.96+or-0.03 AA is found with nO=4.1+or-0.3. The observed structure is discussed with reference to the ion-water dynamics and is contrasted with that of Ni2+ aqueous solutions." @default.
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- W1493783459 date "1988-03-20" @default.
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- W1493783459 title "The structure of Cu<sup>2+</sup>aqueous solutions" @default.
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- W1493783459 doi "https://doi.org/10.1088/0022-3719/21/8/010" @default.
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