FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1493983194> ?p ?o ?g. }

• W1493983194 endingPage "5907" @default.
• W1493983194 startingPage "5895" @default.
• W1493983194 abstract "Abstract A series of new acyl‐functionalized molybdenum(II) complexes [(η 3 ‐C 3 H 5 )(η 5 ‐C 5 H 4 COR)Mo(CO) 2 ] have been successfully synthesized and crystallographically characterized, and the relationship between the reactivity and electronic properties of these organometallic compounds has been studied in detail. The X‐ray analysis revealed [(η 3 ‐C 3 H 5 )(η 5 ‐C 5 H 4 COCF 3 )Mo(CO) 2 ] to exist as a rare endo conformer, the first time that this structure has been observed in the crystal lattice of a [(η 3 ‐C 3 H 5 )(η 5 ‐Cp′)Mo(CO) 2 ] (Cp′ = substituted Cp) complex without any disorder. It has also been demonstrated that the derivatives bearing very strong electron‐withdrawing acyl groups (e.g., ‐CHO, ‐COCF 3 ) show different outcomes in the protonation reactions compared with the parent cyclopentadienyl compound or derivatives bearing less electron‐withdrawing groups (e.g., ‐COMe, ‐COPh). This study has also revealed the increased reactivity of the formyl derivative [(η 3 ‐C 3 H 5 )(η 5 ‐C 5 H 4 CHO)Mo(CO) 2 ] towards aromatic amines. An IR spectroscopic analysis revealed that the aldimine‐functionalized products formed very quickly even under the mild conditions that fulfill the basic rules of click chemistry." @default.
• W1493983194 created "2016-06-24" @default.
• W1493983194 creator A5008003104 @default.
• W1493983194 creator A5023648016 @default.
• W1493983194 creator A5024312158 @default.
• W1493983194 creator A5070043313 @default.
• W1493983194 creator A5028733267 @default.
• W1493983194 date "2014-10-30" @default.
• W1493983194 modified "2023-10-10" @default.
• W1493983194 title "Acyl‐Functionalized Molybdenum Compounds [(η ³ ‐C ₃ H ₅ )(η ⁵ ‐Cp′)Mo(CO) ₂ ]: An Experimental Study Including the X‐ray Structure of a Rare <i>endo</i> Conformer" @default.
• W1493983194 cites W1539796472 @default.
• W1493983194 cites W1556726364 @default.
• W1493983194 cites W1582879365 @default.
• W1493983194 cites W1969301215 @default.
• W1493983194 cites W1973913395 @default.
• W1493983194 cites W1975271459 @default.
• W1493983194 cites W1978541911 @default.
• W1493983194 cites W1980635446 @default.
• W1493983194 cites W1980706690 @default.
• W1493983194 cites W1983994374 @default.
• W1493983194 cites W1984609507 @default.
• W1493983194 cites W1991155248 @default.
• W1493983194 cites W1992689192 @default.
• W1493983194 cites W1996060363 @default.
• W1493983194 cites W2002038098 @default.
• W1493983194 cites W2003177720 @default.
• W1493983194 cites W2010617308 @default.
• W1493983194 cites W2012952812 @default.
• W1493983194 cites W2013222602 @default.
• W1493983194 cites W2016020339 @default.
• W1493983194 cites W2019027552 @default.
• W1493983194 cites W2021850481 @default.
• W1493983194 cites W2026041973 @default.
• W1493983194 cites W2031252009 @default.
• W1493983194 cites W2032842297 @default.
• W1493983194 cites W2033494692 @default.
• W1493983194 cites W2035272084 @default.
• W1493983194 cites W2036508655 @default.
• W1493983194 cites W2038801811 @default.
• W1493983194 cites W2040301309 @default.
• W1493983194 cites W2040630936 @default.
• W1493983194 cites W2047848459 @default.
• W1493983194 cites W2052813845 @default.
• W1493983194 cites W2068369018 @default.
• W1493983194 cites W2069191927 @default.
• W1493983194 cites W2075646446 @default.
• W1493983194 cites W2079776729 @default.
• W1493983194 cites W2080182825 @default.
• W1493983194 cites W2085663309 @default.
• W1493983194 cites W2086403088 @default.
• W1493983194 cites W2086531787 @default.
• W1493983194 cites W2091135387 @default.
• W1493983194 cites W2106227686 @default.
• W1493983194 cites W2111301708 @default.
• W1493983194 cites W2115445294 @default.
• W1493983194 cites W2122261636 @default.
• W1493983194 cites W2124923230 @default.
• W1493983194 cites W2160356350 @default.
• W1493983194 cites W2319062039 @default.
• W1493983194 cites W2320670212 @default.
• W1493983194 cites W2329747064 @default.
• W1493983194 cites W2334933502 @default.
• W1493983194 cites W2949645502 @default.
• W1493983194 cites W2952267912 @default.
• W1493983194 cites W2952662095 @default.
• W1493983194 cites W4205719906 @default.
• W1493983194 doi "https://doi.org/10.1002/ejic.201402700" @default.
• W1493983194 hasPublicationYear "2014" @default.
• W1493983194 type Work @default.
• W1493983194 sameAs 1493983194 @default.
• W1493983194 citedByCount "6" @default.
• W1493983194 countsByYear W14939831942015 @default.
• W1493983194 countsByYear W14939831942016 @default.
• W1493983194 countsByYear W14939831942017 @default.
• W1493983194 countsByYear W14939831942018 @default.
• W1493983194 countsByYear W14939831942022 @default.
• W1493983194 crossrefType "journal-article" @default.
• W1493983194 hasAuthorship W1493983194A5008003104 @default.
• W1493983194 hasAuthorship W1493983194A5023648016 @default.
• W1493983194 hasAuthorship W1493983194A5024312158 @default.
• W1493983194 hasAuthorship W1493983194A5028733267 @default.
• W1493983194 hasAuthorship W1493983194A5070043313 @default.
• W1493983194 hasConcept C115624301 @default.
• W1493983194 hasConcept C142724271 @default.
• W1493983194 hasConcept C145148216 @default.
• W1493983194 hasConcept C155647269 @default.
• W1493983194 hasConcept C161790260 @default.
• W1493983194 hasConcept C178790620 @default.
• W1493983194 hasConcept C181458950 @default.
• W1493983194 hasConcept C185592680 @default.
• W1493983194 hasConcept C204787440 @default.
• W1493983194 hasConcept C2776910235 @default.
• W1493983194 hasConcept C30095370 @default.
• W1493983194 hasConcept C32909587 @default.
• W1493983194 hasConcept C549387045 @default.
• W1493983194 hasConcept C71240020 @default.
• W1493983194 hasConcept C71924100 @default.
• W1493983194 hasConcept C8010536 @default.

• next