FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1494519238> ?p ?o ?g. }

• W1494519238 endingPage "8642" @default.
• W1494519238 startingPage "8638" @default.
• W1494519238 abstract "Horseradish peroxidase will catalyze the chlorination of certain substrates by sodium chlorite through an intermediate known as compound X. A chlorite-derived chlorine atom is known to be retained by compound X and has been proposed to be located at the heme active site. Although several heme structures have been proposed for compound X, including an Fe(IV)-OCl group, preliminary data previously reported by our laboratory suggested that compound X contained a heme Fe(IV) = O group, based on the similarity of a compound X resonance Raman band at 788 cm-1 to resonance Raman Fe(IV) = O stretching vibrations recently identified for horseradish peroxidase compound II and ferryl myoglobin. Isotopic studies now confirm that the 788 cm-1 resonance Raman band of compound X is, in fact, due to a heme Fe(IV) = O group, with the oxygen atom derived from chlorite. The Fe(IV) = O frequency of compound X, of horseradish peroxidase isoenzymes B and C, undergoes a pH-induced frequency shift, with behavior which appears to be the same as that previously reported for compound II, formed from the same isoenzymes. These observations strongly suggest that compounds II and X have very similar, if not identical, heme structures. The chlorine atom thus appears not to be heme-bound and may rather be located on an amino acid residue. The studies on compound X reported here were done in a pH region above pH 8, where compound X is moderately stable. The present results do not necessarily apply to compound X below pH 8." @default.
• W1494519238 created "2016-06-24" @default.
• W1494519238 creator A5033778565 @default.
• W1494519238 creator A5045200437 @default.
• W1494519238 creator A5088272758 @default.
• W1494519238 date "1986-07-01" @default.
• W1494519238 modified "2023-09-30" @default.
• W1494519238 title "Comparison of the heme structures of horseradish peroxidase compounds X and II by resonance Raman spectroscopy." @default.
• W1494519238 cites W1480600051 @default.
• W1494519238 cites W1486937943 @default.
• W1494519238 cites W1489687040 @default.
• W1494519238 cites W1507264433 @default.
• W1494519238 cites W1526744355 @default.
• W1494519238 cites W1536296409 @default.
• W1494519238 cites W1555150960 @default.
• W1494519238 cites W1577138064 @default.
• W1494519238 cites W1588708529 @default.
• W1494519238 cites W1603277938 @default.
• W1494519238 cites W1640960776 @default.
• W1494519238 cites W1873287651 @default.
• W1494519238 cites W1977963003 @default.
• W1494519238 cites W1983817318 @default.
• W1494519238 cites W1984707942 @default.
• W1494519238 cites W2006328183 @default.
• W1494519238 cites W2008517323 @default.
• W1494519238 cites W2020804414 @default.
• W1494519238 cites W2036642060 @default.
• W1494519238 cites W2047854050 @default.
• W1494519238 cites W2052679197 @default.
• W1494519238 cites W2053591502 @default.
• W1494519238 cites W2058145757 @default.
• W1494519238 cites W2059108419 @default.
• W1494519238 cites W2062536367 @default.
• W1494519238 cites W2073295002 @default.
• W1494519238 cites W2074378489 @default.
• W1494519238 cites W2074392919 @default.
• W1494519238 cites W2078052190 @default.
• W1494519238 cites W2085276728 @default.
• W1494519238 cites W2151748867 @default.
• W1494519238 cites W2167734314 @default.
• W1494519238 cites W2256439395 @default.
• W1494519238 cites W2318627548 @default.
• W1494519238 cites W2329828193 @default.
• W1494519238 cites W3004604051 @default.
• W1494519238 cites W3004806768 @default.
• W1494519238 doi "https://doi.org/10.1016/s0021-9258(19)84427-7" @default.
• W1494519238 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/3722164" @default.
• W1494519238 hasPublicationYear "1986" @default.
• W1494519238 type Work @default.
• W1494519238 sameAs 1494519238 @default.
• W1494519238 citedByCount "16" @default.
• W1494519238 countsByYear W14945192382013 @default.
• W1494519238 countsByYear W14945192382017 @default.
• W1494519238 countsByYear W14945192382023 @default.
• W1494519238 crossrefType "journal-article" @default.
• W1494519238 hasAuthorship W1494519238A5033778565 @default.
• W1494519238 hasAuthorship W1494519238A5045200437 @default.
• W1494519238 hasAuthorship W1494519238A5088272758 @default.
• W1494519238 hasBestOaLocation W14945192381 @default.
• W1494519238 hasConcept C109214941 @default.
• W1494519238 hasConcept C120665830 @default.
• W1494519238 hasConcept C121332964 @default.
• W1494519238 hasConcept C139210041 @default.
• W1494519238 hasConcept C162008176 @default.
• W1494519238 hasConcept C181199279 @default.
• W1494519238 hasConcept C185592680 @default.
• W1494519238 hasConcept C20705724 @default.
• W1494519238 hasConcept C2776217839 @default.
• W1494519238 hasConcept C2777676563 @default.
• W1494519238 hasConcept C2781340169 @default.
• W1494519238 hasConcept C32891209 @default.
• W1494519238 hasConcept C40003534 @default.
• W1494519238 hasConcept C46141821 @default.
• W1494519238 hasConcept C55493867 @default.
• W1494519238 hasConcept C62520636 @default.
• W1494519238 hasConcept C75473681 @default.
• W1494519238 hasConceptScore W1494519238C109214941 @default.
• W1494519238 hasConceptScore W1494519238C120665830 @default.
• W1494519238 hasConceptScore W1494519238C121332964 @default.
• W1494519238 hasConceptScore W1494519238C139210041 @default.
• W1494519238 hasConceptScore W1494519238C162008176 @default.
• W1494519238 hasConceptScore W1494519238C181199279 @default.
• W1494519238 hasConceptScore W1494519238C185592680 @default.
• W1494519238 hasConceptScore W1494519238C20705724 @default.
• W1494519238 hasConceptScore W1494519238C2776217839 @default.
• W1494519238 hasConceptScore W1494519238C2777676563 @default.
• W1494519238 hasConceptScore W1494519238C2781340169 @default.
• W1494519238 hasConceptScore W1494519238C32891209 @default.
• W1494519238 hasConceptScore W1494519238C40003534 @default.
• W1494519238 hasConceptScore W1494519238C46141821 @default.
• W1494519238 hasConceptScore W1494519238C55493867 @default.
• W1494519238 hasConceptScore W1494519238C62520636 @default.
• W1494519238 hasConceptScore W1494519238C75473681 @default.
• W1494519238 hasIssue "19" @default.
• W1494519238 hasLocation W14945192381 @default.
• W1494519238 hasOpenAccess W1494519238 @default.
• W1494519238 hasPrimaryLocation W14945192381 @default.
• W1494519238 hasRelatedWork W124639247 @default.

• next