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- W1495164945 abstract "Abstract The “catalytic nitrosyl effect” operating in reversible nitrosyl bending governs the performance of NO‐functionalized chlororhenium derivatives as catalysts in 1‐hexene hydrogenation reactions. Structural support for a Lewis acid (LA) induced bending at the N NO atom was provided by terminal attachment of a Lewis acid to one of the nitrosyl ligands in the [ReCl(PR 3 ) 2 (NO) 2 ] complexes ( 2 : R = i Pr a , R = Cy b ) to give the products [ReCl(PR 3 ) 2 (NO)(NO‐LA)][Z] { 3 : LA = B(C 6 F 5 ) 3 ; 4 : LA = Et + ; Z = [B(C 6 F 5 ) 4 ] – ; 5a : LA = SiEt 3 + , Z = [HB(C 6 F 5 ) 3 ] – ; R = i Pr a , Cy b }. X‐ray diffraction studies revealed a moderately bent nitrosyl ligand in the nonderivatized complex 2a [159.3(5)°] and fully bent NO‐LA groups in 3a [131.4(3)°] and 4b [132.7(3)°]. The catalytic activities of the chloro dinitrosyl complexes in the hydrogenation of prototypical 1‐hexene were investigated. The NO‐LA bent complexes 3b and 4b furnished excellent TONs of up to 1.0 × 10 4 and high TOFs of up to 5.4 × 10 4 h –1 when the Lewis acids were present as co‐catalysts." @default.
- W1495164945 created "2016-06-24" @default.
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- W1495164945 date "2013-12-03" @default.
- W1495164945 modified "2023-10-17" @default.
- W1495164945 title "Structural Evidence for Lewis Acid Triggered Nitrosyl Bending in Rhenium(–I) Chloro Catalysts for Alkene Hydrogenation Reactions" @default.
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- W1495164945 doi "https://doi.org/10.1002/ejic.201301174" @default.
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