FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1495518496> ?p ?o ?g. }

• W1495518496 endingPage "1258" @default.
• W1495518496 startingPage "1251" @default.
• W1495518496 abstract "Collision-induced intersystem crossing rate constants from the (0,4,1) and (1,2,1) levels of the à 1A2 to ã 3B1 state and rovibronic relaxation rate constants in the à 1A2 state of SO2 have been studied. The laser wavelength was set at 335.86 and 334.09 nm for the (0,4,1) and (1,2,1) excitation, respectively. When a few rotational levels belonging to the (0,4,1) and (1,2,1) vibrational levels were populated by a narrow bandwidth laser, both the fluorescence from the à 1A2 state and the phosphorescence from the ã 3B1 state were observed from the time resolved emission spectra. The decay behavior of the fluorescence signal showed fast and slow components. The radiative lifetimes and apparent quenching rate constants obtained from the fast component analysis are 38±5 and (9.8±0.2)×10−10 for (0,4,1) excitation and 33±5 μs and (1.0±0.1)×10−9 cm3 mol−1 s−1 for (1,2,1) excitation, respectively. The effective lifetimes and quenching rate constants for the slow component are 280±100 and (1.5±0.1)×10−10 for (0,4,1) excitation and they are 220±100 μs and (1.6±0.1)×10−10 cm3 mol−1 s−1 for (1,2,1) excitation. Based on the measured rate constants, kinetic simulations of the emission profiles were done to obtain the magnitudes of intersystem crossing and rovibronic relaxation rate constants. The magnitudes of the rovibronic relaxation and the intersystem crossing rate constants are found to be in the range of 8.5–10.0×10−10 and 1.3–1.5×10−10 cm3 mol−1 s−1, respectively." @default.
• W1495518496 created "2016-06-24" @default.
• W1495518496 creator A5010179050 @default.
• W1495518496 creator A5018701685 @default.
• W1495518496 creator A5066695698 @default.
• W1495518496 date "1998-07-22" @default.
• W1495518496 modified "2023-09-24" @default.
• W1495518496 title "Intersystem crossing rate constants from the (0,4,1) and (1,2,1) levels of the à 1A2 to ã 3B1 state of SO2" @default.
• W1495518496 cites W1696950305 @default.
• W1495518496 cites W1964402328 @default.
• W1495518496 cites W1967381241 @default.
• W1495518496 cites W1970342994 @default.
• W1495518496 cites W1971259945 @default.
• W1495518496 cites W1972993275 @default.
• W1495518496 cites W1991037636 @default.
• W1495518496 cites W1991045376 @default.
• W1495518496 cites W2000255311 @default.
• W1495518496 cites W2016910216 @default.
• W1495518496 cites W2019496847 @default.
• W1495518496 cites W2027685852 @default.
• W1495518496 cites W2036059105 @default.
• W1495518496 cites W2037336320 @default.
• W1495518496 cites W2041464580 @default.
• W1495518496 cites W2048128689 @default.
• W1495518496 cites W2059839201 @default.
• W1495518496 cites W2060515222 @default.
• W1495518496 cites W2062144013 @default.
• W1495518496 cites W2063763196 @default.
• W1495518496 cites W2067549091 @default.
• W1495518496 cites W2071111692 @default.
• W1495518496 cites W2071472639 @default.
• W1495518496 cites W2071576748 @default.
• W1495518496 cites W2080470407 @default.
• W1495518496 cites W2088769908 @default.
• W1495518496 cites W2094041591 @default.
• W1495518496 cites W1981279493 @default.
• W1495518496 doi "https://doi.org/10.1063/1.476712" @default.
• W1495518496 hasPublicationYear "1998" @default.
• W1495518496 type Work @default.
• W1495518496 sameAs 1495518496 @default.
• W1495518496 citedByCount "5" @default.
• W1495518496 countsByYear W14955184962013 @default.
• W1495518496 countsByYear W14955184962014 @default.
• W1495518496 crossrefType "journal-article" @default.
• W1495518496 hasAuthorship W1495518496A5010179050 @default.
• W1495518496 hasAuthorship W1495518496A5018701685 @default.
• W1495518496 hasAuthorship W1495518496A5066695698 @default.
• W1495518496 hasBestOaLocation W14955184962 @default.
• W1495518496 hasConcept C113196181 @default.
• W1495518496 hasConcept C120665830 @default.
• W1495518496 hasConcept C121332964 @default.
• W1495518496 hasConcept C121745418 @default.
• W1495518496 hasConcept C148898269 @default.
• W1495518496 hasConcept C15744967 @default.
• W1495518496 hasConcept C181500209 @default.
• W1495518496 hasConcept C184779094 @default.
• W1495518496 hasConcept C185592680 @default.
• W1495518496 hasConcept C2776029896 @default.
• W1495518496 hasConcept C33062035 @default.
• W1495518496 hasConcept C43617362 @default.
• W1495518496 hasConcept C62520636 @default.
• W1495518496 hasConcept C73978554 @default.
• W1495518496 hasConcept C77805123 @default.
• W1495518496 hasConcept C83581075 @default.
• W1495518496 hasConcept C91881484 @default.
• W1495518496 hasConcept C93391505 @default.
• W1495518496 hasConceptScore W1495518496C113196181 @default.
• W1495518496 hasConceptScore W1495518496C120665830 @default.
• W1495518496 hasConceptScore W1495518496C121332964 @default.
• W1495518496 hasConceptScore W1495518496C121745418 @default.
• W1495518496 hasConceptScore W1495518496C148898269 @default.
• W1495518496 hasConceptScore W1495518496C15744967 @default.
• W1495518496 hasConceptScore W1495518496C181500209 @default.
• W1495518496 hasConceptScore W1495518496C184779094 @default.
• W1495518496 hasConceptScore W1495518496C185592680 @default.
• W1495518496 hasConceptScore W1495518496C2776029896 @default.
• W1495518496 hasConceptScore W1495518496C33062035 @default.
• W1495518496 hasConceptScore W1495518496C43617362 @default.
• W1495518496 hasConceptScore W1495518496C62520636 @default.
• W1495518496 hasConceptScore W1495518496C73978554 @default.
• W1495518496 hasConceptScore W1495518496C77805123 @default.
• W1495518496 hasConceptScore W1495518496C83581075 @default.
• W1495518496 hasConceptScore W1495518496C91881484 @default.
• W1495518496 hasConceptScore W1495518496C93391505 @default.
• W1495518496 hasIssue "4" @default.
• W1495518496 hasLocation W14955184961 @default.
• W1495518496 hasLocation W14955184962 @default.
• W1495518496 hasOpenAccess W1495518496 @default.
• W1495518496 hasPrimaryLocation W14955184961 @default.
• W1495518496 hasRelatedWork W2015653434 @default.
• W1495518496 hasRelatedWork W2036639385 @default.
• W1495518496 hasRelatedWork W2038389563 @default.
• W1495518496 hasRelatedWork W2043376873 @default.
• W1495518496 hasRelatedWork W2047488268 @default.
• W1495518496 hasRelatedWork W2047905520 @default.
• W1495518496 hasRelatedWork W2080470407 @default.
• W1495518496 hasRelatedWork W2100937456 @default.
• W1495518496 hasRelatedWork W2149450256 @default.

• next