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- W1495681034 abstract "Allylic organopotassium compounds prepared by metalation of olefins with trimethylsilylmethylpotassium reacted with chlorodiethylborane and B-chloroborinane to give allylic diethylboranes and B-allylic borinanes, respectively. Hydrolysis of these organoboranes proceeding with allylic rearrangement leads to isomerized olefins. In this way, (E,Z)-2-pentene, (Z)-2-heptene, 1-methylcyclohexene and (+)-α-pinene were cleanly transformed into 1-pentene, 1-heptene, methylenecyclohexane and (+)-β-pinene, respectively. Stereochemistry of the addition of myrtenyldiethylborane to formaldehyde and 2-cyclohexenyldiethylborane to 4-t-butylcyclohexanone is described." @default.
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- W1495681034 date "1985-09-01" @default.
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- W1495681034 title "Synthesis with organoboranes" @default.
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- W1495681034 doi "https://doi.org/10.1016/0022-328x(85)80282-5" @default.
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