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• W1496481655 abstract "The room temperature (x, y) two-dimensional phase diagram of the olivine-type solid-solution, orthorhombic, is determined. The x-dependent changes in the unit cell dimensions at various fixed Mn contents y are analyzed in detail. The manganese substitution for iron in the octahedral 4c sites induces 1, the two-phase redox region with a potential of 4.1 V vs. 2, a partial conversion of the form of the redox reaction (3.4 V vs. from two-phase to single-phase; and 3, phase instability at the composition region close to the point (x, y) = (0, 1) caused by the Jahn-Teller effect of The conversion, 2, is complete at around The phase instability, 3, makes the Mn-rich phase unsuitable for battery applications. The local lattice deformation around is severe enough to induce significant selective damping in the extended X-ray absorption fine structure for © 2001 The Electrochemical Society. All rights reserved." @default.
• W1496481655 created "2016-06-24" @default.
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• W1496481655 date "2001-01-01" @default.
• W1496481655 modified "2023-09-25" @default.
• W1496481655 title "Phase Diagram of Li[sub x](Mn[sub y]Fe[sub 1−y])PO[sub 4] (0≤x, y≤1)" @default.
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• W1496481655 doi "https://doi.org/10.1149/1.1401083" @default.
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