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- W1496607979 abstract "Theoretical description of diffusion growth of a gas bubble after its nucleation in supersaturated liquid solution is p resented. We study the influence of Laplace pressure on the bubble growt h. We consider two different solubility laws: Henry’s law, whi ch is fulfilled for the systems where no gas molecules dissociat ion takes place and Sievert’s law, which is fulfilled for the syst ems where gas molecules completely dissociate in the solvent into two parts. We show that the difference between Henry’s and Sievert’s laws for chemical equilibrium conditions causes the difference in bubble growth dynamics. Assuming that diffusion flux of dissolved gas molecules to the bubble is steady we obtain differential equations on bubble radius for both solubility la ws. For the case of homogeneous nucleation of a bubble, which takes place at a significant pressure drop bubble dynamics equatio ns for Henry’s and Sievert’s laws are solved analytically. For both solubility laws three characteristic stages of bubble grow th are marked out. Intervals of bubble size change and time intervals of these stages are found. We also obtain conditions of diffusion flux steadiness corresponding to consecutive stages. The fu lfillment of these conditions is discussed for the case of nucleation of water vapor bubbles in magmatic melts. For Sievert’s law the analytical treatment of the problem of bubble dissolution in a pure solvent is also presented." @default.
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- W1496607979 date "2009-08-01" @default.
- W1496607979 modified "2023-09-27" @default.
- W1496607979 title "Gas bubble growth dynamics in a supersaturated solution: Henry's and Sievert's solubility laws" @default.
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