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- W149684709 abstract "ClCH2(CH2)3CH2Cl reacts with lithium/sodium-alloy (1% sodium) and ZnCl2 in ether (Et2O) to give {Li(Et2O)2}2Zn(CH2(CH2)3CH2)2 (1) (yield 80%). DTA investigations showed that thermal decomposition of 1 takes place at 172°C. By addition of (CH3)2NC2H4N(CH3)2 (tmed) to 1 in ether, {Li(tmed)}2Zn(CH2(CH2)3CH2)2 (2) was formed. Both complexes were characterized by 1H and 13C NMR spectroscopy and 2 by X-ray diffraction methods. ClCH2(CH2)3CH2Cl reagiert mit Lithium/Natrium-Legierung (1% Natrium) in Gegenwart von ZnCl2 in Ether (Et2O) in ca. 80%iger Ausbeute zu {Li(Et2O)2Zn(CH2(CH2)3CH2)2 (1). Wie DTA-Untersuchungen zeigten, zersetzt sich 1 bei 172°C. In Ether reagiert 1 mit (CH3)2NC2H4N(CH3)2 (tmed) zu {Li(tmed)}2Zn(CH2(CH2)3CH2)2 (2). Beide Komplexe wurden 1H- und 13C-NMR-spektroskopisch sowie 2 röntgenstrukturanalytisch charakterisiert." @default.
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- W149684709 date "1992-12-01" @default.
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- W149684709 title "Beiträge zur chemie organometallischer metallacyclischer nebengruppenmetallverbindungen" @default.
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- W149684709 doi "https://doi.org/10.1016/0022-328x(92)83377-t" @default.
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