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- W1497152413 abstract "A new method is suggested for characterization of selectivity in reversed-phase liquid chromatography. It makes use of selectivity scale, calibrated by a reference homologous series (n-alkylbenzenes), and of toluene as the reference standard. The selectivitiy is comprised of lipophilic and polar contributions, which are characterized quantitatively by constants related to the solute structure. For certain types of compounds, these constants can be calculated from the additive increments of structural substituents. In diagrams, where the constants Δq, characterizing the polar contribution to selectivity in one binary solvent system (such as acetonitrile—water), are plotted as a function of Δ in another binary solvent system (such as methanol—water), the compounds with an equal functional group occupy narrow, limited areas and can be distiguished from compounds with other functional groups. This may offer an aid to the identification of functional gropus in simple organic compounds from reversed-phase chromatographic data." @default.
- W1497152413 created "2016-06-24" @default.
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- W1497152413 date "1986-02-01" @default.
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- W1497152413 title "Method for chromaterization of selectivity in reversed-phase liquid chromatography" @default.
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- W1497152413 doi "https://doi.org/10.1016/s0021-9673(01)83372-0" @default.
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