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- W1497249589 abstract "This report is concerned mainly with the results obtained on ozone in power plant plumes. Aerosol production in power plant plumes is discused only briefly. Thirty sets of airborne measurements have been obtained in the plumes from two coal-fired and two gas-fired power plants situated in different climatological areas. On no occasion was above ambient ozone found to be generated in a power plant plume out to distances at which the plume was still distinguishable from the ambient air. These field observations can be understood as follows. The precursors of ozone in fossil fuel power plants are nitrogen oxides, primarily nitric oxide. Nitric oxide must be converted to nitrogen dioxide in the plume before ozone can be produced. An analysis of the field data reveals that this conversion rate is generally controlled by the rate at which a plume mixes with the ambient air rather than by the relevant chemical reaction rates. Since this mixing rate is slower than the chemical reaction rates for the production of ozone, the conversion of nitric oxide to nitrogen dioxide (and hence to ozone) is slower than would be expected from laboratory or smog chamber experiments. The conversion rates are slow enough to makemore » ozone production in power plant plumes unlikely. As far as the production of aerosol from gases in power plant plumes is concerned, field measurements indicate a rather slow conversion rate (about 0.3% per hour).« less" @default.
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- W1497249589 date "1976-09-01" @default.
- W1497249589 modified "2023-09-22" @default.
- W1497249589 title "Reactions of nitrogen oxides, ozone and sulfur in power plant plumes" @default.
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