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- W1497282851 abstract "The conditions of preparation of montmorillonite pillared by titanium polycations have been obtained. This Ti-PILC shows a surface area of 350 m2/g, micropore volume of 0.16 mL/g, basal spacing of 2.4 nm, is stable up to 773 K and then the characteristics of a true PILC. It has been used in the gas phase for the conversion of isopropanol at 373 K and exhibits essentially an acid behaviour with a significant selectivity to ether, attributed to a high Lewis acidity. In the liquid phase, it is a good catalyst for the epoxidation of allylic alcohols with t-butyl hydroperoxide in presence of (+) diethyl tartrate. The yields to the corresponding epoxides are comparable to those reported in the literature. The determination of the enantiomeric excess in the product show some participation of asymetric catalysis." @default.
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- W1497282851 date "2000-01-01" @default.
- W1497282851 modified "2023-09-24" @default.
- W1497282851 title "Characterization and catalytic properties of titanium pillared clays in the epoxidation of allylic alcohols" @default.
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- W1497282851 doi "https://doi.org/10.1016/s0167-2991(00)80436-x" @default.
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