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- W1497402071 abstract "Fast potassium atoms donate an electron to CCl3NO2 molecules to form K+ ions and the negative ions O−, Cl−, NO2−, CCl3−, CCl2NO2−, CCl3NO−, and CCl3NO2−. Threshold energies are measured for these ions and electron affinities for CCl2NO2−, CCl3NO−, and CCl3NO2− are estimated to be 2.35, 2.35, and 1.89 eV (±0.6 eV), respectively. The threshold energies show that the C–N and N–O bonds are substantially weaker than in nitromethane. The CCl3NO2 molecules are oriented before the collision and at energies near 2.5 eV the electron appears to transfer to the π∗NO orbital forming the parent negative ion, CCl3NO2−, which is stabilized by interacting with the K+ donor. As the collision energy increases the parent negative ion fragments and the orientation dependence of the fragment ions helps understand the fragmentation pathway." @default.
- W1497402071 created "2016-06-24" @default.
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- W1497402071 date "2010-01-27" @default.
- W1497402071 modified "2023-10-17" @default.
- W1497402071 title "Crossed-beam studies of electron transfer to oriented trichloronitromethane, CCl3NO2, molecules" @default.
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- W1497402071 doi "https://doi.org/10.1063/1.3299280" @default.
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