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• W1497431405 abstract "We present a unified approach to thermodynamic description of one, two, and three dimensional phases and phase transformations among them. The approach is based on a rigorous definition of a phase applicable to thermodynamic systems of any dimensionality. Within this approach, the same thermodynamic formalism can be applied for the description of phase transformations in bulk systems, interfaces, and line defects separating interface phases. For both lines and interfaces, we rigorously derive an adsorption equation, the phase coexistence equations, and other thermodynamic relations expressed in terms of generalized line and interface excess quantities. As a generalization of the Gibbs phase rule for bulk phases, we derive phase rules for lines and interfaces and predict the maximum number of phases than may coexist in systems of the respective dimensionality." @default.
• W1497431405 created "2016-06-24" @default.
• W1497431405 creator A5058582694 @default.
• W1497431405 creator A5060215106 @default.
• W1497431405 date "2015-07-28" @default.
• W1497431405 modified "2023-10-17" @default.
• W1497431405 title "Phases, phase equilibria, and phase rules in low-dimensional systems" @default.
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• W1497431405 doi "https://doi.org/10.1063/1.4927414" @default.
• W1497431405 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26233156" @default.
• W1497431405 hasPublicationYear "2015" @default.
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