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- W1497481470 abstract "There has been concern as to whether an unconfined combustible cloud arising from the release of liquefied natural gas could detonate. Accordingly, a laboratory scale experimental program and accompanying theoretical treatment were initiated to evaluate this possibility. A sector of a cylindrical cloud was modeled by a special shock tube. Blast waves of variable strength were transmitted into the combustible mixture of interest. Since methane-air couldn't be detonated, the critical initiation energy requirements for various stoichiometric methane-oxygen-nitrogen mixtures were determined and then extrapolated to determine the value for methane-air. Extremely high values were indicated. Inasmuch as natural gas commonly contains ethane and/or propane, stoichiometric mixtures containing various percentages of these gases were tested. Small additions of either (but ethane moreso than propane) reduced the critical initiation energy appreciably, although the values were still quite high. The analytical study shed much light on the competing chemical kinetic and gas dynamic processes. The analysis allowed planar, cylindrical, and spherical geometries to be considered. Further, it independently predicted the characteristics observed experimentally, thus supporting the experimental results." @default.
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- W1497481470 date "1980-05-01" @default.
- W1497481470 modified "2023-09-27" @default.
- W1497481470 title "Initiation of detonation in unconfined natural gas-air clouds : final report" @default.
- W1497481470 hasPublicationYear "1980" @default.
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