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- W1498435631 abstract "The application of thermal and photochemical rearrangements of α,α'-diphenylpyridylazidomethanes to the synthesis of 4-pyridyldibenzoheteroazepines is reported. This route provides easily the 11-(4-pyridyl)dibenzo[b,f][1,4]oxazepine and the 11-(4-pyridyl)dibenzo[b,f][1,4]thiazepine with good yields. In the case of the 11-(4-pyridyl)dibenzo[b,f][1,4]selenazepine this route is less interesting because of the instability of this compound. The previously proposed mechanisms for the thermal and photochemical rearrangements of α,α'-diphenylazidomethanes can be applied to the azides examined." @default.
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- W1498435631 date "1984-09-01" @default.
- W1498435631 modified "2023-09-27" @default.
- W1498435631 title "Study of the azide ion reactivity towards heterocyclic cations. VII. Application of thermal and photochemical rearrangements of α,α'-diphenylpyridylazidomethanes to the syntheses of 4-pyridyldibenzoheteroazepines" @default.
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- W1498435631 doi "https://doi.org/10.1002/jhet.5570210515" @default.
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