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- W1498455105 abstract "Oxidative methylation of toluene with methane was studied over a series of X type zeolite catalysts modified simultaneously with different amount of (Ba+Li). The conversion of toluene, selectivity and yield of C8 hydrocarbons (ethylbenzene and styrene) over the catalyst containing (2.4×10−3mol Ba+2.4×10−3mol Li) per 1 g NaX zeolite is the highest, without deactivation for 27 h, at a given standard reaction condition. The catalytic behavior of this sample is related to its highest basicity measured by temperature-programmed desorption of CO2. The best performance of the (2.4×10−3mol Ba+2.4×10−3mol Li)/g NaX sample is ascribed to the high surface concentration of basic extraframework species BaO and LiCl (detected by X-ray diffraction analysis and X-ray photoelectron spectroscopy) appropriately distributed in the completely preserved structure of the catalyst." @default.
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- W1498455105 date "2005-01-01" @default.
- W1498455105 modified "2023-09-24" @default.
- W1498455105 title "Characterization of the activity and basicity of X type zeolite catalysts modified simultaneously with Ba and Li" @default.
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- W1498455105 doi "https://doi.org/10.1016/s0167-2991(05)80544-0" @default.
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