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- W1498664694 abstract "The results of siudies concerning the radiation sulfoxidation of n- paraffins fraction C/sub 14/-- C/sub 17/ are presented. Paraffins containing about 0.001% aromatic compounds and about 0.0025 mg/ml moisture required a minimal amount of energy to initiate the reaction, viz. 250 to 300 rads. In the same manner as the ionizing radiation act other initiators such as visible light and uv radiation. After initiation, the reaction proceeds spontaneously, provided the properly dried gaseous reactants are conveyed to the reactor. The reaction is essentially influenced by the relation of the effective surface of a reactor to the volume of reacting paraffins. Additionally, it has been shown that the reaction proceeding in the spiral reactor can not be initiated even by a dose of 1.75 Mrad, whereas in the typical reactor 0.3 Mrad dose is sufficient. The relation of alkyl sulfonic acids to that of sulfuric acid yield increased in the course of this process. (auth)" @default.
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- W1498664694 date "1973-01-01" @default.
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- W1498664694 title "Radiation sulfoxidation of n-paraffins. II" @default.
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