FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1498972697> ?p ?o ?g. }

• W1498972697 endingPage "113" @default.
• W1498972697 startingPage "107" @default.
• W1498972697 abstract "The kinetics of the sensitized (O2(1Δg)-mediated) photo-oxidation of tryptophan (trp) and a series of trp-alkyl esters were studied in Triton X-100 micellar solutions employing time-resolved phosphorescence detection of O2(1Δg) and static photolysis. The characterization of the solute-micelle interaction indicates that trp-methyl ester, trp-butyl ester and trp-octyl ester bind Triton X-100 micelles to a different extent, depending on the hydrocarbon length of their ester chains. Trp remains in the aqueous phase. The partition constants vary from 380 for the free amino acid to 11 200 for the octyl-ester derivative. An important decrease in the photo-oxidation quantum efficiency of the esterified compounds was observed due to the presence of the micellar medium. The magnitude of the effect for these solutes, which occupy hydrophobic environments in the micellar structure, is extremely sensitive to the location of the probe and increases as the length of the ester hydrocarbon chain increases. The results, interpreted in terms of the competition between the local oxygen concentration and the solvent polarity effect (the latter representing the driving force), predict a protection against photodynamic damage for trp-containing hydrophobic assemblies in organized biological environments compared with the same processes in pure water. The protection increases as the probe becomes more hydrophobic." @default.
• W1498972697 created "2016-06-24" @default.
• W1498972697 creator A5037292443 @default.
• W1498972697 creator A5066757890 @default.
• W1498972697 creator A5068536727 @default.
• W1498972697 creator A5083588129 @default.
• W1498972697 date "1997-04-01" @default.
• W1498972697 modified "2023-10-16" @default.
• W1498972697 title "Kinetic studies of the photosensitized oxidation () of tryptophan-alkyl esters in Triton X-100 micellar solutions" @default.
• W1498972697 cites W1540787508 @default.
• W1498972697 cites W1973088460 @default.
• W1498972697 cites W1974692550 @default.
• W1498972697 cites W1977664662 @default.
• W1498972697 cites W1994032323 @default.
• W1498972697 cites W2000539628 @default.
• W1498972697 cites W2003184171 @default.
• W1498972697 cites W2026278025 @default.
• W1498972697 cites W2031167655 @default.
• W1498972697 cites W2035044547 @default.
• W1498972697 cites W2038191782 @default.
• W1498972697 cites W2041877769 @default.
• W1498972697 cites W205166791 @default.
• W1498972697 cites W2060483715 @default.
• W1498972697 cites W2076283634 @default.
• W1498972697 cites W2085224229 @default.
• W1498972697 cites W2086531913 @default.
• W1498972697 cites W2101036832 @default.
• W1498972697 cites W2114119430 @default.
• W1498972697 cites W2117783323 @default.
• W1498972697 cites W2125307236 @default.
• W1498972697 cites W2949709140 @default.
• W1498972697 cites W2952257214 @default.
• W1498972697 doi "https://doi.org/10.1016/s1011-1344(96)07447-7" @default.
• W1498972697 hasPublicationYear "1997" @default.
• W1498972697 type Work @default.
• W1498972697 sameAs 1498972697 @default.
• W1498972697 citedByCount "20" @default.
• W1498972697 countsByYear W14989726972012 @default.
• W1498972697 countsByYear W14989726972014 @default.
• W1498972697 countsByYear W14989726972015 @default.
• W1498972697 crossrefType "journal-article" @default.
• W1498972697 hasAuthorship W1498972697A5037292443 @default.
• W1498972697 hasAuthorship W1498972697A5066757890 @default.
• W1498972697 hasAuthorship W1498972697A5068536727 @default.
• W1498972697 hasAuthorship W1498972697A5083588129 @default.
• W1498972697 hasConcept C11268172 @default.
• W1498972697 hasConcept C121332964 @default.
• W1498972697 hasConcept C148898269 @default.
• W1498972697 hasConcept C178790620 @default.
• W1498972697 hasConcept C181817918 @default.
• W1498972697 hasConcept C184651966 @default.
• W1498972697 hasConcept C185592680 @default.
• W1498972697 hasConcept C201268389 @default.
• W1498972697 hasConcept C2776706248 @default.
• W1498972697 hasConcept C2779716929 @default.
• W1498972697 hasConcept C2780263894 @default.
• W1498972697 hasConcept C2780471494 @default.
• W1498972697 hasConcept C515207424 @default.
• W1498972697 hasConcept C5342626 @default.
• W1498972697 hasConcept C54582936 @default.
• W1498972697 hasConcept C55493867 @default.
• W1498972697 hasConcept C62520636 @default.
• W1498972697 hasConcept C75473681 @default.
• W1498972697 hasConcept C91881484 @default.
• W1498972697 hasConceptScore W1498972697C11268172 @default.
• W1498972697 hasConceptScore W1498972697C121332964 @default.
• W1498972697 hasConceptScore W1498972697C148898269 @default.
• W1498972697 hasConceptScore W1498972697C178790620 @default.
• W1498972697 hasConceptScore W1498972697C181817918 @default.
• W1498972697 hasConceptScore W1498972697C184651966 @default.
• W1498972697 hasConceptScore W1498972697C185592680 @default.
• W1498972697 hasConceptScore W1498972697C201268389 @default.
• W1498972697 hasConceptScore W1498972697C2776706248 @default.
• W1498972697 hasConceptScore W1498972697C2779716929 @default.
• W1498972697 hasConceptScore W1498972697C2780263894 @default.
• W1498972697 hasConceptScore W1498972697C2780471494 @default.
• W1498972697 hasConceptScore W1498972697C515207424 @default.
• W1498972697 hasConceptScore W1498972697C5342626 @default.
• W1498972697 hasConceptScore W1498972697C54582936 @default.
• W1498972697 hasConceptScore W1498972697C55493867 @default.
• W1498972697 hasConceptScore W1498972697C62520636 @default.
• W1498972697 hasConceptScore W1498972697C75473681 @default.
• W1498972697 hasConceptScore W1498972697C91881484 @default.
• W1498972697 hasIssue "2-3" @default.
• W1498972697 hasLocation W14989726971 @default.
• W1498972697 hasOpenAccess W1498972697 @default.
• W1498972697 hasPrimaryLocation W14989726971 @default.
• W1498972697 hasRelatedWork W1964942718 @default.
• W1498972697 hasRelatedWork W1982124614 @default.
• W1498972697 hasRelatedWork W2011113993 @default.
• W1498972697 hasRelatedWork W2025287818 @default.
• W1498972697 hasRelatedWork W2025482680 @default.
• W1498972697 hasRelatedWork W2030808891 @default.
• W1498972697 hasRelatedWork W2070799778 @default.
• W1498972697 hasRelatedWork W2767362659 @default.
• W1498972697 hasRelatedWork W2949080510 @default.
• W1498972697 hasRelatedWork W2952979462 @default.
• W1498972697 hasVolume "38" @default.

• next