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- W1498980052 abstract "The compounds (π-C5H5)(CO)2LM-X (L = CO, PR3; M = Mo, W; X = BF4, PF6, AsF6, SbF6) react with H2S, p-MeC6H4SH, Ph2S and Ph2SO(L′) to give ionic complexes [(π-C5H5)(CO)2LML′]+ X−. Also sulfur-bridged complexes, [(π-C5H5)(CO)3WSHW(CO)3(π-C5H5)]+ AsF6− and [(π-C5H5)(CO)3M-μ-S2CNCH2Ph-M(CO)3(π-C5H5)], have been obtained. Reactions with SO2 and CS2 have been examined. Die Verbindungen (π-C5H5)(CO)2LM-X (L = CO, PR3; M = Mo, W; X = BF4, PF6, AsF6, SbF6) reagieren mit H2S, p-MeC6H4SH, Ph2S und Ph2SO(L′) zu den ionischen Komplexen [(π-C5H5)(CO)2LML′]+ X−. Auch Schwefel-verbrückte Komplexe, [(π-C5H5)(CO)3WSHW(CO)3(π-C5H5)]+ AsF6− und [(π-C5H5(CO)3M-μ-S2CNCH2Ph-M(CO)3(π-C5H5)], wurden erhalten. Reaktionen mit SO2 und CS2 wurden untersucht." @default.
- W1498980052 created "2016-06-24" @default.
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- W1498980052 date "1985-08-01" @default.
- W1498980052 modified "2023-10-14" @default.
- W1498980052 title "Metallorganische lewissäuren" @default.
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- W1498980052 doi "https://doi.org/10.1016/0022-328x(85)87296-x" @default.
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