Matches in SemOpenAlex for { <https://semopenalex.org/work/W1499013898> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W1499013898 endingPage "3378" @default.
- W1499013898 startingPage "3372" @default.
- W1499013898 abstract "An unexpected lability of the benzyloxycarbonyl (Z) protecting group under mild basic conditions at room temperature is explained by a mechanism based on anchimeric assistance. It is found that the vicinal amide group stabilises the tetrahedral intermediate formed after nucleophilic addition of hydroxide to the carbonyl of the Z group. This effect operates in N-protected tripeptides and tetrapeptides but Z-protected dipeptides are stable under the same conditions due to blockage of the vicinal amide NH by intramolecular H-bonding with the terminal carboxylate moiety." @default.
- W1499013898 created "2016-06-24" @default.
- W1499013898 creator A5043082259 @default.
- W1499013898 creator A5051415333 @default.
- W1499013898 creator A5052925496 @default.
- W1499013898 creator A5055315776 @default.
- W1499013898 date "2014-04-28" @default.
- W1499013898 modified "2023-09-24" @default.
- W1499013898 title "Mechanistic Insight into the Lability of the Benzyloxycarbonyl (Z) Group inN-Protected Peptides under Mild Basic Conditions" @default.
- W1499013898 cites W1453998420 @default.
- W1499013898 cites W1557012298 @default.
- W1499013898 cites W1984266573 @default.
- W1499013898 cites W1987386465 @default.
- W1499013898 cites W2003210552 @default.
- W1499013898 cites W2003837217 @default.
- W1499013898 cites W2024872256 @default.
- W1499013898 cites W2026563214 @default.
- W1499013898 cites W2037782093 @default.
- W1499013898 cites W2070980005 @default.
- W1499013898 cites W2079270004 @default.
- W1499013898 cites W2089426322 @default.
- W1499013898 cites W2091674930 @default.
- W1499013898 cites W2114434009 @default.
- W1499013898 cites W2117624423 @default.
- W1499013898 cites W2134895649 @default.
- W1499013898 cites W2138076421 @default.
- W1499013898 cites W2313282735 @default.
- W1499013898 cites W2328168271 @default.
- W1499013898 cites W4240812634 @default.
- W1499013898 doi "https://doi.org/10.1002/ejoc.201400154" @default.
- W1499013898 hasPublicationYear "2014" @default.
- W1499013898 type Work @default.
- W1499013898 sameAs 1499013898 @default.
- W1499013898 citedByCount "0" @default.
- W1499013898 crossrefType "journal-article" @default.
- W1499013898 hasAuthorship W1499013898A5043082259 @default.
- W1499013898 hasAuthorship W1499013898A5051415333 @default.
- W1499013898 hasAuthorship W1499013898A5052925496 @default.
- W1499013898 hasAuthorship W1499013898A5055315776 @default.
- W1499013898 hasConcept C121349320 @default.
- W1499013898 hasConcept C149997192 @default.
- W1499013898 hasConcept C155647269 @default.
- W1499013898 hasConcept C161790260 @default.
- W1499013898 hasConcept C167392928 @default.
- W1499013898 hasConcept C178790620 @default.
- W1499013898 hasConcept C178907741 @default.
- W1499013898 hasConcept C185592680 @default.
- W1499013898 hasConcept C192604958 @default.
- W1499013898 hasConcept C2775896084 @default.
- W1499013898 hasConcept C2776568683 @default.
- W1499013898 hasConcept C2778074193 @default.
- W1499013898 hasConcept C2778439535 @default.
- W1499013898 hasConcept C2779281246 @default.
- W1499013898 hasConcept C2779746882 @default.
- W1499013898 hasConcept C2780263894 @default.
- W1499013898 hasConcept C2781311116 @default.
- W1499013898 hasConcept C55493867 @default.
- W1499013898 hasConcept C71240020 @default.
- W1499013898 hasConcept C75079739 @default.
- W1499013898 hasConceptScore W1499013898C121349320 @default.
- W1499013898 hasConceptScore W1499013898C149997192 @default.
- W1499013898 hasConceptScore W1499013898C155647269 @default.
- W1499013898 hasConceptScore W1499013898C161790260 @default.
- W1499013898 hasConceptScore W1499013898C167392928 @default.
- W1499013898 hasConceptScore W1499013898C178790620 @default.
- W1499013898 hasConceptScore W1499013898C178907741 @default.
- W1499013898 hasConceptScore W1499013898C185592680 @default.
- W1499013898 hasConceptScore W1499013898C192604958 @default.
- W1499013898 hasConceptScore W1499013898C2775896084 @default.
- W1499013898 hasConceptScore W1499013898C2776568683 @default.
- W1499013898 hasConceptScore W1499013898C2778074193 @default.
- W1499013898 hasConceptScore W1499013898C2778439535 @default.
- W1499013898 hasConceptScore W1499013898C2779281246 @default.
- W1499013898 hasConceptScore W1499013898C2779746882 @default.
- W1499013898 hasConceptScore W1499013898C2780263894 @default.
- W1499013898 hasConceptScore W1499013898C2781311116 @default.
- W1499013898 hasConceptScore W1499013898C55493867 @default.
- W1499013898 hasConceptScore W1499013898C71240020 @default.
- W1499013898 hasConceptScore W1499013898C75079739 @default.
- W1499013898 hasIssue "16" @default.
- W1499013898 hasLocation W14990138981 @default.
- W1499013898 hasOpenAccess W1499013898 @default.
- W1499013898 hasPrimaryLocation W14990138981 @default.
- W1499013898 hasRelatedWork W1993985228 @default.
- W1499013898 hasRelatedWork W1994086798 @default.
- W1499013898 hasRelatedWork W2015700143 @default.
- W1499013898 hasRelatedWork W2042532296 @default.
- W1499013898 hasRelatedWork W2051899534 @default.
- W1499013898 hasRelatedWork W2072802431 @default.
- W1499013898 hasRelatedWork W2083710050 @default.
- W1499013898 hasRelatedWork W2088480953 @default.
- W1499013898 hasRelatedWork W2095681830 @default.
- W1499013898 hasRelatedWork W2793484199 @default.
- W1499013898 hasVolume "2014" @default.
- W1499013898 isParatext "false" @default.
- W1499013898 isRetracted "false" @default.
- W1499013898 magId "1499013898" @default.
- W1499013898 workType "article" @default.