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- W1499054420 abstract "Abstract The intermolecular energies of n -alkane solute molecules in n -alkane solvents at infinite dilution have been determined by gas-liquid chromatography. According to the quasi-lattice model, the intermolecular energies of solute molecules can be expressed as the sum of interaction energies of each pair of a segment of the molecules with segments of neighbouring molecules. The interaction energies of contact pairs of CH 3 -CH 3 , CH 3 -CH 2 and CH 2 -CH 2 have been estimated by an equation derived from a theory of solute-solvent interactions. A consistent set of the values was found for all of the solute-solvent systems studied without the need to adjust the model parameters." @default.
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- W1499054420 date "1975-02-01" @default.
- W1499054420 modified "2023-10-10" @default.
- W1499054420 title "Thermodynamic properties of solute molecules at infinite dilution determined by gas-liquid chromatography" @default.
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- W1499054420 doi "https://doi.org/10.1016/s0021-9673(01)82256-1" @default.
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