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- W1499172257 abstract "We introduce a kinetic model for the growth of epitaxial graphene on 6$H$-SiC(0001). The model applies to vicinal surfaces composed of half-unit-cell-height steps where experimental results show that step flow sublimation of SiC promotes the formation and growth of graphene strips parallel to the step edges. The model parameters are effective energy barriers for the nucleation and subsequent propagation of graphene at the step edges. Using kinetic Monte Carlo simulations and rate equations, two distinct growth regimes emerge from a study of the layer coverage and distribution of top-layer graphene strip widths as a function of total coverage, vicinal angle, and the model parameters. One regime is dominated by the coalescence of strips. The other regime is dominated by a ``climbover'' process, which facilitates the propagation of graphene from one terrace to the next. Comparing our results to scanning microscopy studies will provide the first quantitative insights into the kinetics of growth for this unique epitaxial system." @default.
- W1499172257 created "2016-06-24" @default.
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- W1499172257 date "2011-09-27" @default.
- W1499172257 modified "2023-09-25" @default.
- W1499172257 title "Model for the epitaxial growth of graphene on 6<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>H</mml:mi></mml:math>-SiC(0001)" @default.
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- W1499172257 doi "https://doi.org/10.1103/physrevb.84.115459" @default.
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