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- W1499913802 abstract "Purified BF3-etherate reacts with 3β-acetoxy-5,6α-epoxy-5α-cholestane(I) at high concentrations in benzene to give the unsymmetrical di-steroidal ether (IIa). The formation of the ether (IIa) involves a novel “backbone rearrangement” of one of the steroidal skeletons, giving the 5β,14β-dimethyl 18,19-bisnor structure with all ring junction configurations inverted. 3,3-Ethylene dioxy-5,6β-epoxy-5β-cholestane reacts with BF3-etherate to give the rearranged monomeric product (IVd), among other products. 3β,5,6β-Triacetoxy-5α-cholestane undergoes a similar “backbone” shift on treatment with BF3-etherate in acetic anhydride at 80°." @default.
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- W1499913802 date "1966-01-01" @default.
- W1499913802 modified "2023-10-09" @default.
- W1499913802 title "Reaction of epoxides—XI" @default.
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- W1499913802 doi "https://doi.org/10.1016/s0040-4020(01)82300-0" @default.
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