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- W1501471076 abstract "Substitution of benzene by N-benzene- and N-(4-methylbenzenesulfonyl)hydroxylamines occurs in the presence of phosphorous pentoxide whereas N-methyl-N-benzenesulfonylhydroxylamine gave no substitution product under the same conditions. When N-(4-methylbenzenesulfonyl)hydroxylamine was treated with phosphorous pentoxide in pyridine, N-(4-methylbenzenesulfonimido)pyridinium ylide was formed. Nitrene intermediates are postulated to account for these products. Similarly carbazole was formed from 2-hydroxylamino[1,1′-biphenyl] and phosphorous pentoxide but with phosphorous pentachloride, 3- and 3-chloro-2-amino[1,1′-biphenyls] were formed, most likely via a nitrenium ion intermediate." @default.
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- W1501471076 date "1975-01-01" @default.
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- W1501471076 title "Aromatic substitution by N-arylhydroxylamines—II" @default.
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- W1501471076 doi "https://doi.org/10.1016/0040-4020(75)80214-6" @default.
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