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- W1502155209 abstract "Abstract A series of chromium(II) complexes containing the tripodal ligands tmpa, Me 2 uns‐penp, Me 4 apme and Me 6 tren were prepared and investigated with regard to their reactivity towards dioxygen. It was possible to structurally characterize the complexes [Cr(Me 2 uns‐penp)Cl] 2 (BPh 4 ) 2 , [Cr(Me 6 tren)Cl]Cl, [Cr(Me 4 apme)Cl]BPh 4 and [Cr(Me 4 ampe)Cl 3 ]. The complexes show reactions with dioxygen, but it was not possible to characterize intermediates of these reactions. The oxidation behavior of the complexes towards organic substrates like toluene was investigated and oxidation of toluene to benzaldehyde was observed." @default.
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- W1502155209 date "2013-08-15" @default.
- W1502155209 modified "2023-09-23" @default.
- W1502155209 title "Investigation of Chromium Complexes with a Series of Tripodal Ligands" @default.
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- W1502155209 doi "https://doi.org/10.1002/zaac.201300170" @default.
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