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- W1502437697 abstract "We have synthesized a few monomeric silicon compounds bearing benzyl, diphenylmethyl, 9,10-dihydroanthacenyl, 9-fluorenyl, 2,2-diphenylethyl, phenyl or tert-butyl groups, which are characterized by NMR data, and in several cases additionally by single crystal X-ray diffraction. Moreover, in some substances the silicon atoms are bridged by -CH2-CH2- or -CC- units. All synthesized compounds, which exclusively contain the elements silicon, carbon, and hydrogen, should be suitable as precursors for silicon-alloyed carbon fibers, while they could be co-pyrolised, if necessary after previous polymerization (catalytic dehydrogenative or by intermolecular hydrosilylation), in a mixture with the polyaromatic mesophase (PA-MP) to yield modified carbons. The latter investigation takes place in cooperation with the group of Prof. K. J. Hiittinger, Karlsruhe. The introduction of silicon improves strength, hardness, and oxidation resistance of these pyrolytically-prepared materials, so that in this way completely new applications are possible." @default.
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- W1502437697 date "2005-07-26" @default.
- W1502437697 modified "2023-10-03" @default.
- W1502437697 title "Precursors for Silicon‐Alloyed Carbon Fibers" @default.
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- W1502437697 doi "https://doi.org/10.1002/9783527620777.ch100b" @default.
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