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- W1502642486 abstract "A novel route with L-ascorbic acid as a single common starting material to asymmetric synthesis of all eight diastereomers of L-hexoses is described. Assessment of this new approach is demonstrated by the expedient synthesis of L-galactopyranose and L-talopyranose derivatives. Key steps involve stereoselective preparation of chiral (E)- and (Z)-γ-hydroxy-α,β-unsaturated esters and their stereo-controlled dihydroxylation by OsO4." @default.
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- W1502642486 date "2003-11-01" @default.
- W1502642486 modified "2023-09-23" @default.
- W1502642486 title "Novel Route toL-Hexoses fromL-Ascorbic Acid: Asymmetric Synthesis ofL-Galactopyranose andL-Talopyranose Preliminary Communication" @default.
- W1502642486 doi "https://doi.org/10.1002/hlca.200390302" @default.
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