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- W1502890997 abstract "The electrochemical behaviour of p-benzoquinone dioxime on Pt electrodes modified by underpotentially-deposited heavy metal monolayers has been studied in aqueous HClO4 solutions by employing cyclic voltammetric and rotating-disc or ring-disc techniques. p-Benzoquinone dioxime undergoes both oxidation and reduction. The oxidation is a simple two-electron process producing p-dinitrosobenzene. The reduction is a rather complicated reaction producing p-phenylenediamine. It involves three charge-transfer steps separated by two chemical steps within an ECECE mechanism. The chemical steps are dehydration reactions of intermediate hydroxylamines. The electroactive intermediates, generated by the slow chemical reactions, are more easily reducible than the original reactant, thus leading to kinetically-controlled limiting current densities. The rate constants of the chemical reactions were determined from rotating-disc and ring-disc data. Moreover, we present a theoretical treatment for the ECECE mechanism for potential step chronoamperometry." @default.
- W1502890997 created "2016-06-24" @default.
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- W1502890997 date "1988-12-01" @default.
- W1502890997 modified "2023-10-18" @default.
- W1502890997 title "A reaction model for the ECECE mechanism" @default.
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- W1502890997 doi "https://doi.org/10.1016/0022-0728(88)87045-1" @default.
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