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- W1503041611 abstract "Four kinds of thio derivatives of β-diketone and their nickel, cobalt, zinc, palladium, copper, lead, rhodium and iron chelates were prepared. The ratio of metal to ligand was 1 : 3 in cobalt, rhodium and iron chelates and 1 : 2 in other metal chelates. Bromination of cobalt chelates by N-bromosuccinimide or bromine were successful in some cases to give tribrominated chelates. Comparison of cobalt thio-β-diketonates with their tribrominated chelates in infrared and nuclear magnetic resonance spectra indicated that the bromination took place at γ-carbon of chelate ring. The success of the bromination can be considered as a kind of support for quasiaromaticity of the chelate to some extent." @default.
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- W1503041611 date "1970-01-01" @default.
- W1503041611 modified "2023-10-12" @default.
- W1503041611 title "Studies on the Sulfur-containing Chelating Agents. XXII. Some Metal Chelates of Thio-β-diketones and Bromination of Cobalt (III) Thio-β-diketonates" @default.
- W1503041611 doi "https://doi.org/10.1248/cpb.18.356" @default.
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