FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1503072076> ?p ?o ?g. }

• W1503072076 abstract "Abstract Selected ‘3+1’ mixed ligand oxorhenium and oxotechnetium complexes containing the SNS/S donor atom set have been modified by introduction of a bifunctional amine anchor on the p -position of the thiophenolato monodentate ligand. A representative series of complexes containing several tridentate ligands was prepared both at macromolar (Re complexes) and nanomolar ( 99m Tc complexes) amounts. Coupling of these complexes to activated carboxylate groups was performed according to the ‘preformed chelate approach’ using benzoyl chloride as a model molecule. Coupling yields were high both at nanomolar and millimolar metal concentration, as revealed by high-performance liquid chromatographic analysis of 99m Tc and Re species adopting parallel radiometric and photometric detection modes. All Re compounds have been characterized by classical analytical methods. In addition, the structures of representative parent ReO[CH 3 SCH 2 CH 2 N(CH 2 CH 2 S) 2 ][ p -SC 6 H 4 NH 2 ] and daughter ReO[CH 3 SCH 2 CH 2 N(CH 2 CH 2 S) 2 ][ p -SC 6 H 4 NHCOC 6 H 5 ] complexes were solved by X-ray crystallography. Both compounds adopt a distorted trigonal bipyramidal geometry around rhenium, wherein the oxo group and the sulfur atoms of the SNS ligand occupy the equatorial plane and the nitrogen atom and the sulfur of the monothiol are located at the apical positions trans to each other." @default.
• W1503072076 created "2016-06-24" @default.
• W1503072076 creator A5006363758 @default.
• W1503072076 creator A5029897786 @default.
• W1503072076 creator A5039883783 @default.
• W1503072076 creator A5052894337 @default.
• W1503072076 creator A5056238048 @default.
• W1503072076 creator A5057711091 @default.
• W1503072076 creator A5076378923 @default.
• W1503072076 creator A5079838266 @default.
• W1503072076 creator A5085663976 @default.
• W1503072076 date "1999-11-01" @default.
• W1503072076 modified "2023-10-03" @default.
• W1503072076 title "A ‘preformed chelate approach’ model for coupling amine-modified rhenium and technetium ‘3+1’ mixed ligand complexes to carboxylate residues" @default.
• W1503072076 cites W1486978767 @default.
• W1503072076 cites W2005486693 @default.
• W1503072076 cites W2011171294 @default.
• W1503072076 cites W2015724154 @default.
• W1503072076 cites W2021438826 @default.
• W1503072076 cites W2024140289 @default.
• W1503072076 cites W2043351579 @default.
• W1503072076 cites W2047434638 @default.
• W1503072076 cites W2051760313 @default.
• W1503072076 cites W2068803243 @default.
• W1503072076 cites W2079055909 @default.
• W1503072076 cites W2087941813 @default.
• W1503072076 cites W2090252042 @default.
• W1503072076 cites W2115481151 @default.
• W1503072076 cites W2171560270 @default.
• W1503072076 cites W230298216 @default.
• W1503072076 cites W617072219 @default.
• W1503072076 doi "https://doi.org/10.1016/s0277-5387(99)00286-7" @default.
• W1503072076 hasPublicationYear "1999" @default.
• W1503072076 type Work @default.
• W1503072076 sameAs 1503072076 @default.
• W1503072076 citedByCount "7" @default.
• W1503072076 countsByYear W15030720762012 @default.
• W1503072076 crossrefType "journal-article" @default.
• W1503072076 hasAuthorship W1503072076A5006363758 @default.
• W1503072076 hasAuthorship W1503072076A5029897786 @default.
• W1503072076 hasAuthorship W1503072076A5039883783 @default.
• W1503072076 hasAuthorship W1503072076A5052894337 @default.
• W1503072076 hasAuthorship W1503072076A5056238048 @default.
• W1503072076 hasAuthorship W1503072076A5057711091 @default.
• W1503072076 hasAuthorship W1503072076A5076378923 @default.
• W1503072076 hasAuthorship W1503072076A5079838266 @default.
• W1503072076 hasAuthorship W1503072076A5085663976 @default.
• W1503072076 hasConcept C111592845 @default.
• W1503072076 hasConcept C115624301 @default.
• W1503072076 hasConcept C116569031 @default.
• W1503072076 hasConcept C131779359 @default.
• W1503072076 hasConcept C155647269 @default.
• W1503072076 hasConcept C158842870 @default.
• W1503072076 hasConcept C161790260 @default.
• W1503072076 hasConcept C170493617 @default.
• W1503072076 hasConcept C178516000 @default.
• W1503072076 hasConcept C178790620 @default.
• W1503072076 hasConcept C179104552 @default.
• W1503072076 hasConcept C185592680 @default.
• W1503072076 hasConcept C197404232 @default.
• W1503072076 hasConcept C2778074193 @default.
• W1503072076 hasConcept C2780443040 @default.
• W1503072076 hasConcept C505216180 @default.
• W1503072076 hasConcept C55493867 @default.
• W1503072076 hasConcept C71240020 @default.
• W1503072076 hasConcept C8010536 @default.
• W1503072076 hasConceptScore W1503072076C111592845 @default.
• W1503072076 hasConceptScore W1503072076C115624301 @default.
• W1503072076 hasConceptScore W1503072076C116569031 @default.
• W1503072076 hasConceptScore W1503072076C131779359 @default.
• W1503072076 hasConceptScore W1503072076C155647269 @default.
• W1503072076 hasConceptScore W1503072076C158842870 @default.
• W1503072076 hasConceptScore W1503072076C161790260 @default.
• W1503072076 hasConceptScore W1503072076C170493617 @default.
• W1503072076 hasConceptScore W1503072076C178516000 @default.
• W1503072076 hasConceptScore W1503072076C178790620 @default.
• W1503072076 hasConceptScore W1503072076C179104552 @default.
• W1503072076 hasConceptScore W1503072076C185592680 @default.
• W1503072076 hasConceptScore W1503072076C197404232 @default.
• W1503072076 hasConceptScore W1503072076C2778074193 @default.
• W1503072076 hasConceptScore W1503072076C2780443040 @default.
• W1503072076 hasConceptScore W1503072076C505216180 @default.
• W1503072076 hasConceptScore W1503072076C55493867 @default.
• W1503072076 hasConceptScore W1503072076C71240020 @default.
• W1503072076 hasConceptScore W1503072076C8010536 @default.
• W1503072076 hasLocation W15030720761 @default.
• W1503072076 hasOpenAccess W1503072076 @default.
• W1503072076 hasPrimaryLocation W15030720761 @default.
• W1503072076 hasRelatedWork W186691869 @default.
• W1503072076 hasRelatedWork W1977354187 @default.
• W1503072076 hasRelatedWork W2008780063 @default.
• W1503072076 hasRelatedWork W2009261996 @default.
• W1503072076 hasRelatedWork W2013860119 @default.
• W1503072076 hasRelatedWork W2019045673 @default.
• W1503072076 hasRelatedWork W2028054333 @default.
• W1503072076 hasRelatedWork W2033428267 @default.
• W1503072076 hasRelatedWork W2035951547 @default.
• W1503072076 hasRelatedWork W2036943590 @default.
• W1503072076 hasRelatedWork W2044410799 @default.
• W1503072076 hasRelatedWork W2074290640 @default.

• next