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- W1504077338 abstract "A new Co(II) cluster, {[CoL(DMF)]2(OAc)2Co}·2DMF (H2L = 4,4′-dichloro-2,2′-[(1,3-propylene)dioxybis (nitrilomethylidyne)]diphenol), has been synthesized and characterized by elemental analysis, IR spectrum, UV–Vis spectrum, and X-ray diffraction method. The results indicate that the Co(II) cluster consists of three Co(II) ions, two tetradentate (μ-L) 2− units, two coordinated μ-acetate ions, two coordinated DMF, and two crystallizing DMF molecules. All the hexa-coordinated Co(II) ions of the Co(II) cluster have a slightly distorted octahedral geometry. The crystal packing of the Co(II) cluster shows that a notable feature of this structure resides in the formation of a novel 2D supramolecular structure through intermolecular C‒H···O interaction and weak intramolecular C‒H···(Ph) interaction along the b-axes." @default.
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- W1504077338 date "2011-02-19" @default.
- W1504077338 modified "2023-10-18" @default.
- W1504077338 title "Synthesis, Characterization, and Crystal Structure of a Tri-nuclear Cobalt(II) Cluster" @default.
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- W1504077338 doi "https://doi.org/10.1080/15533174.2010.538030" @default.
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