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• W1504108105 abstract "Solid solutions of xBiFeO3–yPrFeO3–zPbTiO3 (x+y+z=1) and (1−w)BiFeO3–wPbTiO3 have been explored for finding ferroelectromagnetic bulk material, in which ferroelectricity and ferromagnetism coexist simultaneously. The coexistence has been observed only in some ternary composition samples, that is, 0.2BiFeO3–0.2PrFeO3–0.6PbTiO3 and 0.4BiFeO3–0.2PrFeO3–0.4PbTiO3. In the ternary solid solutions, spontaneous magnetic moments disappear with the decrease of PrFeO3 content to y&lt;0.2 independently of BiFeO3 content. When PrFeO3 content remains constant at y=0.2, the ternary solid solutions become paraelectric with the decrease of PbTiO3 content to z⩽0.2. The ferroelectromagnetic solid solutions have the noncentrosymmetric and doubled perovskite unit cell with a space group I4cm (a=b≈5.4 Å, c≈7.9 Å). Addition of Ta2O5 dopant substantially changes the polarization–electric-field and magnetization–magnetic field curves of the 0.2BiFeO3–0.2PrFeO3–0.6PbTiO3. The binary solid solutions of (1−w)BiFeO3–wPbTiO3 do not exhibit spontaneous magnetic moments down to 10 K over the entire composition range." @default.
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• W1504108105 date "2003-05-19" @default.
• W1504108105 modified "2023-09-23" @default.
• W1504108105 title "Ferroelectric and ferromagnetic properties of BiFeO3–PrFeO3–PbTiO3 solid solutions" @default.
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• W1504108105 doi "https://doi.org/10.1063/1.1567818" @default.
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