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- W1504609243 abstract "The ruthenium(II)-catalyzed sp3 C-H bond arylation of benzylic amines with aryl halides is reported. In the present method, aryl iodides and, more importantly, also the cheaper aryl bromides and aryl chlorides can be applied as aryl sources. Additionally, the method does not require elaborate manipulations in a glove box and can be carried out in simple screw cap vials. Potassium pivalate proved to be beneficial for the transformation with aryl bromides or iodides as aryl source, but was not required for aryl chlorides. In the latter case, the addition of PPh3 led to high conversion. 3-Methyl and 3-phenyl pyridine were established as directing groups, and the substituent in the 3-position represents a key structural feature for high conversion. The directing group can be cleaved after the transformation, which allows access to diarylmethylamines. Mechanistic studies were carried out and critically compared to mechanistic reports of related transformations." @default.
- W1504609243 created "2016-06-24" @default.
- W1504609243 creator A5002091128 @default.
- W1504609243 creator A5019600527 @default.
- W1504609243 creator A5066135839 @default.
- W1504609243 date "2013-03-22" @default.
- W1504609243 modified "2023-10-17" @default.
- W1504609243 title "Aryl Bromides and Aryl Chlorides for the Direct Arylation of Benzylic Amines Mediated by Ruthenium(II)" @default.
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- W1504609243 doi "https://doi.org/10.1002/ejoc.201300004" @default.
- W1504609243 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3698694" @default.
- W1504609243 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23847437" @default.
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