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- W1504657155 abstract "Abstract The oxidation of p-xylene in acetic acid a using cobalt(III)-bromide system or in conjunction with pyridine was studied under inert atmosphere. It was found that in the presence of p-xylene the preferential reaction of Co-(III) with Br− also produces molecular bromine or the complex PyBr2 which brominates the hydrocarbon. The formation of side-chain brominated products is suppressed in the presence of Co(II) and Co(III) ions or pyridine, probably as a result of the competitive reaction of intermediately formed ArCH2 radicals with Co(III) ions instead of bromine radicals. In the reaction mechanism, bromine anion radicals are assumed to initiate p-xylene oxidation and reoxidize Co(II) ions. The presence of pyridine in the reaction system facilitates the regeneration of Co(III) and bromide ions." @default.
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- W1504657155 date "1986-10-01" @default.
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- W1504657155 title "Study of p-xylene reaction with Co-Br-pyridine catalyst" @default.
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- W1504657155 doi "https://doi.org/10.1016/0304-5102(86)85023-4" @default.
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