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- W1504890382 abstract "/sup 14/N/sup 15/N relative to /sup 14/N/sup 14/N and /sup 16/O/sup 18/O relative to /sup 16/O/sup 16/O. These cross section ratios differ from unity, a difference which can be explained by considering nuclear mass effects on the Franck-Condon factors of the molecular transitions. The measured intensities of the /sup 14/N/sup 15/N and /sup 16/O/sup 18/O Q-branches provided the baseline data needed to make the previously-mentioned extrapolation. High-resolution (approximately 0.15 cm/sup -1/) spectra of the Q-branches of /sup 14/N/sup 14/N and /sup 16/O/sup 16/O yielded a direct determination of ..cap alpha../sub e/ (the difference between the rotational constant in the ground and first excited vibrational states) for these molecules. The measured values are in excellent agreement with those obtained by other means. Complete Raman spectra (pure rotation, rotation-vibration, and high-resolution Q-branch) were obtained on a sample of pure /sup 18/O/sup 18/O. Analysis of this data yielded the molecular parameters: the equilibrium internuclear separation r/sub e/, the moment of inertia I/sub e/, and the energy parameters ..cap alpha../sub e/, B/sub e/, and ..delta..G/sub /sup 1///sub 2//. These are in good agreement with data obtained by microwave spectroscopy." @default.
- W1504890382 created "2016-06-24" @default.
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- W1504890382 date "1974-04-18" @default.
- W1504890382 modified "2023-09-26" @default.
- W1504890382 title "Feasibility of isotopic abundance measurements using Raman scattering" @default.
- W1504890382 doi "https://doi.org/10.2172/4325588" @default.
- W1504890382 hasPublicationYear "1974" @default.
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